Chemie, Physikalische Chemie, Gd, Element der Gruppe der Lanthanoide des Periodensystems mit der Ordnungszahl 64. Gadolinium besitzt die Elektronenkonfiguration [Xe]4f145d106s1 und kommt in der Natur in sieben Isotopen vor (Tab. 1).
Gadolinium 1: Wichtige Isotope.
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Isotop |
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Natürliche |
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Atommasse |
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Halbwerts- |
152Gd |
0,20 |
151,919 786 |
1,1 × 1014 a |
153Gd |
0 |
152,921 745 |
241,6 d |
154Gd |
2,18 |
153,920 861 |
stabil |
155Gd |
14,80 |
154,922 618 |
stabil |
156Gd |
20,47 |
155,922 118 |
stabil |
157Gd |
15,65 |
156,923 956 |
stabil |
158Gd |
24,84 |
157,924 049 |
stabil |
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160Gd |
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21,86 |
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159,927 049 |
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stabil |
Gadolinium 2: Allgemeine, chemische und festkörperphysikalische Eigenschaften.
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relative Atommasse (12C = 12,000 0) |
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157,25 |
Dichte (298 K) [g cm-3] |
7,898 |
Molvolumen [cm3] |
19,90 |
Oxidationszahlen |
II, III |
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photoelektrische Arbeit [eV] |
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3,1 |
Gadolinium 3: Thermische und elektromagnetische Eigenschaften.
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Siedetemperatur [K] |
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3506 |
Schmelztemperatur [K] |
1585 |
Siedeenthalpie [kJ mol-1] |
301,9 |
Schmelzenthalpie [kJ mol-1] |
15,5 |
Wärmeleitfähigkeit (300 K) [W m-1K-1] |
10,6 |
spezifische Wärme [kJ kg-1K-1] |
0,23 |
thermischer Längenaus |
8,6 |
spezifischer Widerstand [10-8 Wm] |
134 |
Curie-Temperatur [K] |
289 |
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spezifische magnetische Suszeptibilität [10-5 kg-1m3] |
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6,030 |
Gadolinium 4: Atom- und kernphysikalische Eigenschaften.
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Termsymbol |
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9D2 |
1. Ionisierungsenergie [eV] |
6,15 |
2. Ionisierungsenergie [eV] |
12,09 |
Elektronenaffinität [eV] |
< 0,5 |
Elektronegativität (Pauling) |
1,20 |
effektive Kernladung (Slater) |
2,85 |
Magnetisches Moment [mB] |
6,532 |
Ionenradius (Gd3+) [nm] |
0,094 |
Kovalenzradius [nm] |
0,161 |
Atomradius [nm] |
0,1802 |
Kernspin |
|
kernmagnetisches Moment [mK] |
|
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Einfangquerschnitt für thermische Neutronen [barn] |
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49 000 |
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